However, sometimes a particularly disobedient iOS device requires a firmer hand.įorce restart is ideal for scaring some sense into an iPhone that refuses to cooperate. When to use force restart, recovery, and DFU modeįorce restart, recovery, and DFU mode are only necessary in certain situations, and less aggressive measures will usually solve most issues. You can now use DFU mode to restore your phone, keeping in mind that all data will be lost. If you’ve successfully entered DFU mode, your iPhone’s screen should stay black, and a pop-up will appear on your computer stating that the device must be restored. Release the Side button and continue to hold Volume down for 10 seconds and release.While continuing to hold the Side button, press and hold Volume down for five seconds.Press and hold the Side button for 10 seconds.On a Mac running macOS Catalina or later, open Finder If iTunes is already open, relaunch the app. On a Windows PC or a Mac running macOS Mojave or earlier, open iTunes.Connect your iPhone to a computer using the charging cable.Here’s how to put an iPhone 13 into DFU mode: Generally, you or an Apple technician will use this method when a faulty update or something else has bricked your device. In extreme cases, you may need to use DFU mode to restore a phone that even recovery can’t help. You can exit recovery mode at any time by pressing and holding the Side button until your phone’s screen goes black. Restore erases all information on the device and performs a clean installation of the operating system. Selecting Update updates your iPhone to the latest version of iOS while keeping your data intact. When a recovery mode prompt appears on your computer, select either Update or Restore to begin the process If your iPhone continuously fails to boot after a forced restart, you may need to try recovery mode to update or restore the device. This also works for any iPhone with Face ID, including the iPhone X, iPhone XS, iPhone XR, or any iPhone 11, iPhone 12, or iPhone 13 model. That’s how to force restart your iPhone 13. Finally, press and hold the Side button and release when the Apple logo appears.Press and release the Volume down button. Here’s how to force restart an iPhone 13: You only need to use this method when your device is completely unresponsive. If your iPhone freezes and you can’t switch it off with the side button, force restarting may be the solution. Now that we’ve gotten that disclaimer out of the way, let’s discuss how to force restart and restore a misbehaving iPhone 13. Before we get started, however, this should only be used as a last resort. Special cases may require the more severe-and difficult to enter-Device Firmware Update (DFU) mode.īut don’t worry, we’ll guide you through that process, as well. For serious issues, you’ll need to know how to force restart an iPhone 13 and enter recovery mode When your iPhone 13 misbehaves, you have several solutions for restarting, updating, or restoring the device.
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He began his anchoring duties for the show May 13, 2013. On May 8, 2013, MSNBC announced that CNBC reporter Brian Shactman would be the new regular host of Way Too Early. Both shows had similar graphics packages, are broadcast from the same set, and frequently reference each other. Way Too Early was not branded "Brewed by Starbucks" like Morning Joe until the sponsorship deal expired in September 2013. The original executive producer was Chris Licht, who was also the co-creator and executive producer of Morning Joe before leaving MSNBC to become executive producer of CBS This Morning and Vice President of Programming at CBS. hour of Today, filling the co-host slot formerly held by Savannah Guthrie (who now anchors the 7-9 a.m. On September 24, 2012, NBC News announced that Geist would be named co-host of the 9 a.m. Mike Barnicle often filled in for original host Willie Geist, jokingly referring to the show as " Way Too Old (or Elderly) with Mike Barnicle", while Peter Alexander also covered for Geist. Phil Griffin, President of MSNBC, announced the show on July 15, 2009, and described it as a "pre-game show" for Morning Joe. On October 25, 2021, MSNBC announced that Jonathan Lemire would be the new host of the show. On July 16, 2021, Kasie Hunt announced she was delivering her final broadcast and would be joining CNN. On September 10, 2020, it was announced that Way Too Early would return to the air with Kasie Hunt as the new host, starting on September 21. timeslot had become nearly universally programmed as a morning news slot on local television stations in both the Eastern and Central Time Zones, making the title Way Too Early an artifact. Another apparent reason for the name change was that the 5 a.m. It ended on August 12, 2016, as its lead-in program First Look was expanded back into the full hour and rebranded as Morning Joe First Look to build continuity with the later program. The final host was Chief White House Correspondent Chris Jansing. It was later hosted by a variety of NBC News on-air talent, including Thomas Roberts and others on a temporary basis, including Ayman Mohyeldin. The first incarnation of Way Too Early premiered on July 27, 2009, hosted by Willie Geist. The network has had shows with the title Way Too Early, both with and without the name of the host at the time, during two different time periods. Way Too Early with Jonathan Lemire is an American early morning news show that airs weekday mornings on MSNBC. What is the best horse feed to feed a horse? Equine Senior Active feed contains higher levels of lysine, fat, calcium, phosphorous, copper, selenium, and zinc to support working senior horses. What is the difference between Purina Equine Senior and Purina equine senior active?īecause of this, Equine Senior is lower in calories and contains forage, whereas Equine Senior Active has higher calories and is meant to be fed with hay. Changes in feeding should be made gradually. Meals of ULTIUM® Gastric Care Horse Formula or RACE READY® GT Race Horse Formula include OUTLAST® Gastric Support Supplement, so each meal will count as one OUTLAST® supplement top-dress/snack. Scientifically formulated with a blend of fiber sources including beet pulp and top quality hay to help maintain the senior horse’s body condition and support normal digestive function. Does Purina Equine Senior have beet pulp? In addition, commercially available fat-added concentrates typically contain 5–14% crude fat. What horse feed has the highest fat content?įeedstuffs high in fat include vegetable oils (100%), rice bran (15-18%), flax seeds (30-40%), and heat-treated soybeans (15-22%). Beet pulp is available with or sans added molasses and its soft texture makes it easy for toothless horses to consume. What to feed an old horse who can’t eat hay?Īlternatives to Traditional Hay Adding beet pulp to your horse’s morning meal is one popular way to help them maintain their weight and control their rate of grain consumption.
That’s the only way we can form a π bond between these two carbons we need the p orbital of the carbocation to line up with the pair of electrons from the C-H bond that we’re breaking in the deprotonation step. In our cyclohexane ring here, the hydrogen has to be axial.The leaving group must be anti to the hydrogen that is removed. The Key Requirements Of Stereochemistry In The E2 Reaction Remember this reaction – where one elimination gave the “Zaitsev” product, whereas the other one did not. Now we’re in a position to answer a puzzle that came up when we first looked at elimination reactions. E1 vs E2: Why Does One Elimination Give The “Zaitsev” Product, And The Other Elimination Does Not? The stereochemistry of the hydrogen to be removed must be anti to that of the leaving group the pair of electrons from the breaking C-H bond donate into the antibonding orbital of the C-(leaving group) bond, leading to its loss as a leaving group. A strong base is generally required, one that will allow for displacement of a polar leaving group. The rate of the E2 reaction depends on both substrate and base, since the rate-determining step is bimolecular (concerted). Finally there is no requirement for the stereochemistry of the starting material the hydrogen can be at any orientation to the leaving group in the starting material. Forming the carbocation is the “slow step” a strong base is not required to form the alkene, since there is no leaving group that will need to be displaced (more on that in a second). Hence, the more stable that carbocation is, the faster the reaction will be. The rate of the E1 reaction depends only on the substrate, since the rate limiting step is the formation of a carbocation. Now, let’s also look at how these two mechanisms are different. How Are The E1 and E2 Reactions Different? both reactions follow Zaitsev’s rule (where possible)ģ.in both reactions, a species acts as a base to remove a proton, forming the new π bond.in both cases, we form a new C-C π bond, and break a C-H bond and a C–(leaving group) bond.Here’s what each of these two reactions has in common: What Do The E1 and E2 Reactions Have In Common? Comparing The Mechanism Of The E1 and E2 ReactionsĢ. (Advanced) References and Further Readingġ.The Key Requirements Of Stereochemistry In The E2 Reaction.E1 vs E2: Why Does One Elimination Give The “Zaitsev” Product, And The Other Elimination Does Not?.How Are The E1 and E2 Reactions Different?.What Do The E1 and E2 Reactions Have In Common?.Comparing The Mechanism Of The E1 and E2 Reactions.Now that we’ve gone through the mechanisms of the E1 and E2 reactions, let’s take a moment to look at them side by side and compare them. This only happens if the leaving group is especially poor.E1 versus E2 : Comparing The E1 and E2 Reactions Lastly, under #"E"2#, we have one special reaction called #"E1cB"#, meaning "first-order elimination, forming a conjugate base intermediate". #"E"1# has a carbocation intermediate, which allows for 1,2-hydride shifts or 1,2-alkyl shifts, but #"E"2# does not have or allow either.#"E"1# has no need for an antiperiplanar orientation, but #"E"2# does.Favorable for higher steric hindrance on the electrophile and/or nucleophile.A proton from the #beta# carbon leaves, forming a #pi# bond across a carbon-carbon bond such that the most substituted product is made (Zaitsev's Rule).Second-order would mean that the rate-limiting step involves two molecules. First-order simply means the rate-limiting step involves one molecule only. These are called #"E"1# and #"E"2#, respectively. We have a first-order and a second-order process associated with elimination. Note that they don't necessarily all happen in one step. In general, an elimination reaction (specifically, it's called #beta#-elimination) involves the elimination of a proton from the #beta# carbon, forming a #pi# bond, and ejecting a leaving group. The admiration for Beckham was arguably surpassed two minutes later when Rooney was replaced by Dimitar Berbatov. Milan had been generous enough, and coach Leonardo then gave Old Trafford even more of what it wanted by sending on Beckham for a 27-minute cameo, which was greeted with a rapturous standing ovation. He took a Paul Scholes pass in his stride before evading his marker and burying his finish in the far corner beyond Abbiati. If Milan harboured any hopes of rescuing this lost cause, they were finally snuffed out as Park put United three up on the hour. Great credit must go to Nani, who played in an inviting cross from the left flank with the outside of his right foot for the incoming Rooney to steer another expert finish past Abbiati. Milan's resolve was drastically reduced by this early setback and United were able to take control for the remainder of the half, with Fletcher almost adding a second with a rising drive that was only inches away.īeckham was in the middle of receiving a standing ovation as he warmed up in the opening moments of the second half - only for Rooney to interrupt with United's second and decisive goal. Neville delivered a cross his old friend and former team-mate Beckham would have been proud of, and Rooney maintained his lethal form in the air by flashing a header past Christian Abbiati. United, in the predictable form of Rooney, made them pay for the failure to take those half-chances as they took the lead after 13 minutes. Klaas-Jan Huntelaar then betrayed his reputation as an accomplished marksman with a desperate piece of control with only Van der Sar to beat. Milan had opportunities of their own amid the early sparring, with Ronaldinho's header falling agonisingly wide for Milan after Nani had unwittingly flicked on Andrea Pirlo's free-kick. The England striker was narrowly off target with a shot on the turn from the edge of the area, then the unlikely figure of Neville followed suit with a left-foot effort from long range that dipped just over the bar. Joel and Avi Glazer were in attendance at Old Trafford, and they were left in no doubt about the strength of feeling against their regime as the protests swept around the ground.įletcher's goal interrupted the well-orchestrated demonstration, but as a show of strength it was as impressive as some of United's play as they outclassed Milan.īeckham milked the applause at the final whistle, but he had received a brutal demonstration of the gap between the club he left behind and the one he graces now, albeit on a temporary basis.Īnd Old Trafford's joy was complete as news filtered through that Real Madrid, regarded as one of their major rivals, had fallen at the hands of Lyon in the Bernabeu.īeckham's hopes of celebrating his Old Trafford comeback with a place in Milan's starting line-up were dashed when he was only named on the bench - and he watched anxiously as Rooney posted the early warning signs. Ji-Sung Park drilled in the third on the hour as United exerted complete control.ĭarren Fletcher added the fourth with a diving header from Rafael's cross three minutes from time to put added gloss on a hugely satisfying evening for Sir Alex Ferguson as he bids to take United to the Champions League final for the third season in succession.īeckham made a greater impact than most of his hapless colleagues after his introduction, with some trademark crosses and a full-blooded volley that flew straight at Edwin van der Sar.Īnd with the football business successfully concluded, United's supporters conducted a protest against the Glazer family, with huge banners unfurled around Old Trafford and thousands of green and gold scarves, the symbol of their discontent, on display. Rooney headed United in front from Gary Neville's cross early on and extended United's 3-2 advantage from the first leg even further seconds after half-time after good work by Nani. Media requires JavaScript to play.įerguson enjoys 'fantastic' night for United Texas hunter Products is well known for manufacturing top quality products and their line of fish feeders for lakes and ponds is no different. This feeder is great if you have a small pond or live near your pond and don't mind visiting frequently to keep the feeder filled. The DF125 may be one of the smallest feeders we offer, but that doesn't mean it lacks any features that the big boys offer. Lake & Pond Directional Fish Feeder with Straight Legs - DF125DL These feeders are an investment into your time, just as much as they are an investment into your pond. Keep in mind tho, these feeders are designed to last decades! If having a larger capacity unit is important to you, just buy it. The larger directional units such as the DF425 from Texas Hunter and the AFC425 from Sweeney will be shipped via LTL can be a bit more costly. The DF125 from Texas Hunter and the AFC125 from Sweeney both ship UPS and will be considerably less cost to ship. Size and quantity are the most important factors to consider. Both Texas Hunter and Sweeney are top-of-the-line units! Choosing the right fish feeder ultimately depends on the specific needs of your pond or fishing spot, your budget, and your personal preferences. Texas Hunter and Sweeney fish feeders are both great options for feeding fish in ponds or lakes, but they differ in their design and construction, feed capacity, feed distribution system, and price. Therefore, while the bass themselves may not directly consume the fish food from the automatic feeder, the feeder indirectly contributes to their growth and overall health by providing a consistent food source for the smaller fish they feed on. Additionally, the consistent availability of food can help the bass reach their maximum growth potential.įurthermore, the increased population of smaller fish can also create a more natural and balanced ecosystem in your pond, as they serve as a food source for other aquatic animals such as birds, turtles, and frogs. The smaller fish consume the fish food that is dispensed by the feeder, which in turn increases their population and growth rate.Īs the smaller fish population grows, the bass have a larger and more readily available food source, allowing them to grow larger and healthier. Using an automatic fish feeder on your pond can indirectly help grow bigger bass by providing a consistent food source for smaller fish that the bass feed on. Supplemental feeding can help to provide the necessary nutrition that the fish need to thrive. However, in a pond environment, the amount of natural food available may be limited, especially if the pond is overcrowded or has a low nutrient level. In a natural ecosystem, fish can find their own food by feeding on algae, insects, and other small organisms. Fish that are not getting enough food can become malnourished, weak, and vulnerable to diseases. Supplemental feeding is important for fish in a pond because it ensures that they receive all the necessary nutrients they need to grow and remain healthy. Consistent feeding is key to ensuring your fish grow big and strong. The Importance of Automatic Fish Feedersįirst, let's talk about why automatic fish feeders are so important. Are you ready to take your pond to the next level? Want to grow bigger and healthier bass and bluegill? Well, it's time to invest in a fish feeder! In this article, we'll cover all the details you need to know about using fish feeders to grow healthy and thriving fish in your pond. As a result, the stylus works like a relatively sharp pen-I really can take excellent ink notes using it. It’s that point that your eye sees as your write, and the ink is laid down from that center point. The point that holds the disc is a sharp stylus point that is embedded in the middle of that clear disc. The Jot Pro places a quarter-inch wide clear plastic flat disc on the surface of the iPad, which rotates about at the end of the pen shaft. It works completely different from the others foam-tipped styluses. That’s why I’m so excited about the new stylus that came out a few months ago called the Jot Pro. After trying 2 or 3 new and improved models that still did not meet my needs, I abandoned that quest. Some people could do it more precisely, but it never worked for me. But using those, due to the unwieldy size of the tip, I always ended up creating huge lettering-the size of which, in my mind, made normal note taking almost impossible. And later some companies released styluses that sported broad foam tips that imitated a fingertip. Sure, you could write with your finger tip. So when the iPad came out, I wasn’t happy that it was fairly impractical for electronic ink notes. I did that all the time in business meetings and used it when brainstorming. One of the things I liked best about the Tablet PC, and wrote a lot about, was using it to take good ink notes right on the screen. I don’t recommend you buy it now, it’s horribly out of date and mostly out of print, but I’ve been watching the tablet space closely since then. Many of you may know that I wrote a book in 2004 about the Tablet PC, and it became the best-selling book about the Tablet PC at that time. I feel taking good notes should be a part of any business skill set, and this stylus (called the Jot Pro) in my mind finally makes doing that on an iPad practical.īackground: Tablet PC’s were good at this I’ve finally found a stylus for the iPad that I can take good accurate ink notes with, and I’m really excited about it. When using the Gallery, make sure you’re adhering to our Community Guidelines and Academic Honesty Policy.This is definitely off my normal range of topics but it’s something I’m passionate about and it could be of use to many of you.
Tianhe was successfully launched on 29 April 2021. The Modular Space Station Core Module would be called Tianhe ( Chinese: 天和 pinyin: Tiān Hé lit.Subsequently, Tianzhou 3, Tianzhou 4 and Tianzhou 5 were launched respectively on 20 September 2021, and 12 November 2022. The first mission to the space station, Tianzhou 2, flew on. The first Tianzhou mission successfully launched and deorbited in 2017. The cargo transport spacecraft would be called Tianzhou ( Chinese: 天舟 pinyin: Tiān Zhōu lit.The large modular space station would be called Tiangong as well, without number.Tiangong-1 and Tiangong-2 were launched respectively in 20. The precursor space labs would be called Tiangong ( Chinese: 天宫 pinyin: Tiān Gōng lit.On 31 October 2013, CMSA announced the new names for the whole space station program: We now feel that the public should be involved in the names and symbols, as this major project will enhance national prestige and strengthen the national sense of cohesion and pride". Wang Wenbao, director of the China Manned Space Agency (CMSA), told a news conference in 2011: "Considering past achievements and the bright future, we feel the manned space programme should have a more vivid symbol, and that the future space station should carry a resounding and encouraging name. The rendezvous of the space vehicles has been compared to the reunion of the cowherd and the weaver girl. Across China, the launch of Tiangong-1 was reported to have inspired a variety of feelings, including love poetry. The name "Tiangong" means "heavenly palace". These poetic names continue as the first, second, third, fourth, fifth and future probes of the Chinese Lunar Exploration Program are called Chang'e – after the Moon goddess. Thus, the new Long March launch vehicles were renamed " Divine Arrow - (Shénjiàn - 神箭), space capsule Divine Vessel (Shénzhōu - 神舟), spaceplane Divine Dragon (Shénlóng - 神龙), land-based high-power laser Divine Light (Shénguāng - 神光), and supercomputer Divine Might (Shénwēi - 神威). The names used in the space program, previously all chosen from the revolutionary history of the People's Republic, have been replaced with mystical-religious ones. They took off from the Gobi Desert for an expected 6 month trip. On 2 November 2023 China sent it's youngest ever crew to the Tiangong space station consisting of a crew with only an average age of 38 years old. The space station aims to provide opportunities for space-based experiments and a platform for building capacity for scientific and technological innovation. The first module, the Tianhe ("Harmony of the Heavens") core module, was launched on 29 April 2021, followed by multiple crewed and uncrewed missions and two more laboratory cabin modules Wentian ("Quest for the Heavens") launched on 24 July 2022 and Mengtian ("Dreaming of the Heavens") launched on 31 October 2022. The construction of the station is based on the experience gained from its precursors, Tiangong-1 and Tiangong-2. It is China's first long-term space station, part of the Tiangong program and the core of the "Third Step" of the China Manned Space Program it has a pressurised volume of 340 m 3 (12,000 cu ft), slightly over one third the size of the International Space Station. 'Sky Palace'), officially the Tiangong space station ( Chinese: 天宫空间站 pinyin: Tiāngōng kōngjiānzhàn), is a permanently crewed space station constructed by China and operated by China Manned Space Agency in low Earth orbit between 340 and 450 km (210 and 280 mi) above the surface. Tiangong ( Chinese: 天宫 pinyin: Tiāngōng lit. A rendering of the station with the Tianhe at centre of picture, a Tianzhou on its aft port, the Wentian on its starboard port to the left, the Mengtian on its portside port to the right and two Shenzhou spacecraft, sharing its multi-docking hub Even if you’re not blessed with a setting as charming as Corrigan’s, these essential pieces will help you get his space’s look in no time. So, using Corrigan’s home as a primer, we’ve rounded up seven classic decor elements that every traditional home should have, from lighting and seating to accessories. The combination is bound to make any student of traditional design take notice. 'Porcelain is the ideal option for a timeless floor,' says Bea Pernia, founder of Bea Interior Design. If you have a more traditional home, consider basket weave styles, and for a more modern decor, a herringbone pattern would work best. Given his background as an antiques addict-he once lived behind the City of Light’s most venerable auction house before starting his interiors business back home-the Los Angeles–bred designer unites his maximalist rooms with a timeless collection of heirlooms, from mirrored obelisks to vintage Jansen stools. When it comes to patterns, consider hexagon, stripes, diagonal and checkerboards. Raphael also advises that some elements give your home a timeless yet updated look naturallylighter colors and neutrals. Mandarin Stone s Lavastone basin is created from volcanic boulders sourced from Indonesia, and each basin is unique in size, color and design. In this design by Gioi Tran, streamlined cabinetry and fixtures paired with neutral walls and hardwood floors create a space that will look contemporary for decades to come. Evoke the serenity of the natural world by incorporating raw materials into your traditional bathroom ideas design scheme. 'You can make it fresh by freely mixing antiques and modern pieces that each have a purpose or story to tell,' Raphael says. Part of what gives a room timeless style is the use of classic patterns such as damasks, botanicals, stripes, and plaids. Whether outfitted with traditional details or sleek, modern accents, a white kitchen will stand the test of time. This creates a stylish and timeless look. Napoléon III crystal chandeliers hang from plaster ceilings and gilded mirrors sit above marble mantels, while richly embellished curtains frame sun-drenched windows and vintage rugs cover chevron-planked hardwood floors. An unexpected collection keeps your room from staying stuck in a particular year and adds charm. Modern English interior design is a style that combines British style with contemporary elements. Decorator Timothy Corrigan’s Paris pied-à-terre is a study in traditional design-albeit with a Francophile twist. Please consider becoming one of our patrons. This is the idea which will not work exactly this way because we'll help each other during the process and Lustbringer still needs a lot of images and could take a little longer to complete on the art part than the tower defence being programmed but pretty much sums our plans.ĭo you like our games and want to help us to make possible continue doing them? Our plan working in different projects simultaneously is to advance in both projects and once Root completes all the art for the tower defence, Knot will probably had finished all the code for Lustbringer and will jump on the tower defence, and Root will jump on completing the art of Lusbringer and both Lustbringer Beta and the tower defence will be probably released almost simultaneously at the end of January or during February. Root will be working on the overall minigame mechanics design, the texts it will have, the map, Elana and the villagers, hopefully the sprites of the towers and publishing the animation poll for the game. This week Knot will be focused on prepare the browser and android version of Lustbringer alpha 2, if there is time fix small things found during the testing, like some images misplaced, a couple of things that worked a little clunky and start to adjust things to make the game more agile. While Knot continues to polish and finish the code part of Lustbringer, Root is already starting to work on the new minigame coming from the polls, a tower defence (there's been a bit of changes in the story on this one, elana will no longer be an eccentric billionaire but a beloved mad scientist). Ero Dungeon, Party of Five Vit Ha Free Khm Ph Lng Ngc Cng 5 Hot Girl. Summertime Saga Nhn Vt Lucy Lucy Story Summertime Saga. One Slice of L.u.s.t Ra Khi Cng Nami & Robin Onepiece Game Chill. But today is a new day of a new week for a new work period and this gave us all the mood energy we needed!Īgain, for a while we'll be working in two simultaneous projects. Summertime Saga Nhn Vt Crystal Crystal Story Summertime Saga. As you may know another Lustbringer version was released this weekend with our regular dose of crunch time and extinguishing another of our life tokens as usual. |
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